Johnson, Brian P. and Balàzs, Gàbor and Scheer, Manfred (2004) Complexes with a Metal-Phosphorus Triple Bond. In: Majoral, Jean-Pierre, (ed.) New Aspects in Phosphorus Chemistry IV. Topics in Current Chemistry, 232. Springer, Berlin, pp. 1-23. ISBN 3-540-40883-5.
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A survey of the existing complexes containing a transition metal-phosphorus triple bond is presented. Based on the different types of these complexes—terminal and asymmetrically bridged complexes with a phosphido ligand as well as the linearly coordinated phosphinidene complexes—their characteristic structural and bonding features as well as trends in their NMR data are discussed and compared. The present knowledge of the reactivity pattern of these types of compounds is summarized, which represents a field with tremendous perspectives.
|Item Type:||Book Section|
|Date:||19 February 2004|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||Phosphorus ligand; P NMR spectroscopy; Metathesis; Multiple bonds; Transition metal complexes|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||14 Jun 2010 12:13|
|Last Modified:||20 Jul 2011 22:29|