Startseite UB

Elemental Gallium as a Source of Subvalent Gallium Units in Gallium-Rhodium Clusters [Elementares Gallium als Quelle für niedervalente Gallium-Liganden in neuartigen Ga-Rh-Clustern]

Scheer, Manfred and Kaupp, Martin and Virovets, Alexander V. and Konchenko, Sergej N. (2003) Elemental Gallium as a Source of Subvalent Gallium Units in Gallium-Rhodium Clusters [Elementares Gallium als Quelle für niedervalente Gallium-Liganden in neuartigen Ga-Rh-Clustern]. Angewandte Chemie International Edition 42 (41), pp. 5083-5086.

[img]PDF
Download (189kB) - Repository staff only

at publisher (via DOI)


Abstract

Mild reduction with metals: Elemental gallium is used as mild reducing agent for transition-metal halides to generate subvalent GaCl ligands in novel clusters. In the reaction of Ga with [{CpRhCl2}] (Cp=5-1,3-C5H3tBu2), clusters with GaCl ligands and with unprecedented two-coordinate Ga centers in a multicenter-multiple-bonding interaction between two rhodium centers are formed (see ...

plus


Export bibliographical data



Item Type:Article
Date:22 October 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200351226DOI
Keywords:cluster compounds; electron localization functions; gallium; insertions; rhodium
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:14
Last Modified:13 Mar 2014 13:34
Item ID:15234
Owner Only: item control page

Downloads

Downloads per month over past year

  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact