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An Unusual Bonding Situation in a Novel AuI-Phosphido Complex with a Planar Au3P3 Framework

Vogel, Ulf and Sekar, Perumal and Ahlrichs, Reinhart and Huniar, Uwe and Scheer, Manfred (2003) An Unusual Bonding Situation in a Novel AuI-Phosphido Complex with a Planar Au3P3 Framework. European Journal of Inorganic Chemistry 2003 (8), pp. 1518-1522.

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Abstract

Reaction of the mono-deprotonated derivative of [{Cp(CO)2Mo}2(-PH2)(-H)] (1) leads to the novel complex [{Cp(CO)2Mo}2(-H){3-P(H)Au(PPh3)}] (2). In contrast the reaction of the analogous Cr derivative [{Cp(CO)2Cr}2(-PH2)(-H)] (1a) leads under identical conditions to a planar Au3P3 cluster [{CpCr(CO)2}6(P3Au3)] (3). Both complexes were completely structurally and spectroscopically characterised. ...

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Item Type:Article
Date:2 April 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200390197DOI
Keywords:Metathesis; Cyclopentadienyl ligands; Chromium; P ligands; Gold
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:19
Last Modified:13 Mar 2014 13:35
Item ID:15240
Owner Only: item control page
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