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The Stabilisation of Monomeric Parent Compounds of Phosphanyl- and Arsanylboranes

Vogel, Ulf and Hoemensch, Petra and Schwan, Karl-Christian and Timoshkin, Alexey Y. and Scheer, Manfred (2003) The Stabilisation of Monomeric Parent Compounds of Phosphanyl- and Arsanylboranes. Chemistry - A European Journal 9 (2), pp. 515-519.

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Abstract

The structures of the parent compounds of phosphanyl- and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT-B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2NMe3)] (E=P (3), As (4)) derivatives have been synthesised by the metathesis reactions between Li[(CO)5WEH2] and ClH2BNMe3 (E=P, ...

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Item Type:Article
Date:16 January 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200390054DOI
Keywords:arsenic; boron; density functional calculations; phosphorus; tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:19
Last Modified:13 Mar 2014 13:35
Item ID:15241
Owner Only: item control page

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