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A Synthetic Approach to Novel Group 13/15 Element Complexes

Leiner, Eva and Scheer, Manfred (2002) A Synthetic Approach to Novel Group 13/15 Element Complexes. Organometallics 21 (21), pp. 4448-4453.

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The gallium chloro complex [GaCl{Fe(CO)2Cp}2] (Cp = η5-C5H5) was reacted with KP(SiMe3)2 under special conditions to yield the complexes [{CpFe(CO)}2{μ-(CO)}[μ-Ga{CpFe(CO)2}]] (1) and [{CpFe(CO)2}GaP(SiMe3)]4 (2). Furthermore, [[{CpFe(CO)2}ClGa](μ-PPh2)2FeCpCO] (4) was obtained by the reaction of [GaCl{Fe(CO)2Cp}2] with LiPPh2. Complexes 1, 2, and 4 have been characterized spectroscopically and ...


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Item Type:Article
Date:14 September 2002
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
Subjects:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:20
Last Modified:13 Mar 2014 13:35
Item ID:15242
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