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Synthesis and structure of the novel mixed Sb/Se and Sb/Te containing iron carbonyl clusters [Fe3(μ3-Y)(μ3-SbMes)(CO)9] (Y=Se, Te) and [Fe3(μ3,η2:η1-SeSbMes)(μ3-SbMes)(CO)10]

Konchenko, Sergei N. and Pushkarevsky, Nikolai A. and Scheer, Manfred (2002) Synthesis and structure of the novel mixed Sb/Se and Sb/Te containing iron carbonyl clusters [Fe3(μ3-Y)(μ3-SbMes)(CO)9] (Y=Se, Te) and [Fe3(μ3,η2:η1-SeSbMes)(μ3-SbMes)(CO)10]. Journal of Organometallic Chemistry 658 (1-2), pp. 204-209.

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Abstract

The reaction between the cluster dianion [Fe3(μ3-Y)(CO)9]2− (1) (Y=Se (a), Te (b)) and MesSbBr2 leads to the formation of [Fe3(μ3-Y)(μ3-SbMes)(CO)9] (2a,b) (Mes=2,4,6-Me3C6H2). The molecular structures of both compounds were established by single crystal X-ray diffraction and reveals nido cluster cores containing square pyramidal FeSbFeY units capped by a third Fe carbonyl fragment as an apical ...

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Item Type:Article
Date:16 September 2002
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/S0022-328X(02)01659-5DOI
Keywords:Cluster; Carbonyl complexes; Iron; Antimony; Selenium; Tellurium
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:20
Last Modified:13 Mar 2014 13:35
Item ID:15243
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