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Complexes with a Metal-Phosphorus Triple Bond as Versatile Building Blocks in Coordination and Organometallic Chemistry

Scheer, Manfred and Schiffer, Michael and Leiner, Eva and Johnson, Brian P. and Haindl, Corinna and Umbarkar, Shubhangi (2002) Complexes with a Metal-Phosphorus Triple Bond as Versatile Building Blocks in Coordination and Organometallic Chemistry. Phosphorus, Sulfur, and Silicon and the Related Elements 177 (6-7), pp. 1617-1620.

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Abstract

Trapping reactions of the phosphido complex intermediate [Cp*(CO) 2 W ıP →W(CO) 5 ], generated by thermolysis of [Cp*PlcubW(CO) 5 rcub 2 ] 1 , occur via [2 + 2] cycloaddition reactions with P 4 , phosphaalkynes, alkynes, and [CpMo(CO) 2 ] 2 , respectively. However, with nitriles, insertion reactions into the P--C σbond of 1 are observed already at room temperature to give novel P-containing ...

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Item Type:Article
Date:June 2002
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1080/10426500212300DOI
Keywords:Cyloadditions; Insertion Reactions; Multiple Bonds; P Ligands
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:36
Last Modified:14 Jun 2010 12:36
Item ID:15330
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