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Lewis Acid/Base Stabilized Phosphanylalane and -gallane [Lewis-Säure/Base-stabilisiertes Phosphanylalan und -gallan]

Vogel, Ulf and Timoshkin, Alexey Y. and Scheer, Manfred (2001) Lewis Acid/Base Stabilized Phosphanylalane and -gallane [Lewis-Säure/Base-stabilisiertes Phosphanylalan und -gallan]. Angewandte Chemie International Edition 40 (23), pp. 4409-4412.

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Abstract

Neither synthesis nor detection in matrix isolation experiments has been accomplished for the parent compounds of phosphanylalanes and -gallanes of type A. H2 elimination reactions between [(CO)5WPH3] and H3ENMe3 (E=Al, Ga) have enabled the first synthesis of Lewis acid/base stabilized complexes of the type B. Comprehensive density functional theory (DFT) calculations on the aluminum systems verify the high stability of the complexes of type B.


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Item Type:Article
Date:28 November 2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/1521-3773(20011203)40:23<4409::AID-ANIE4409>3.0.CO;2-FDOI
Keywords:aluminum; density functional calculations; gallium; Lewis acids; phosphorus
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Deposited On:14 Jun 2010 12:37
Last Modified:13 Mar 2014 13:36
Item ID:15333
Owner Only: item control page

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