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Insertion Reactions of Nitriles into the P-C Bond of [(1-C5Me5)P{W(CO)5}2] - A Novel Approach to Phosphorus-Containing Heterocycles

Schiffer, Michael and Scheer, Manfred (2001) Insertion Reactions of Nitriles into the P-C Bond of [(1-C5Me5)P{W(CO)5}2] - A Novel Approach to Phosphorus-Containing Heterocycles. Angewandte Chemie International Edition 40 (18), pp. 3413-3416.

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Abstract

Unexpectedly, nitriles are inserted at room temperature into the unstrained P-C bond of [Cp*P{W(CO)5}2]. Depending on the nitrile used, dihydro-1,3,2-diazaphosphinine and benzo-1,2-azaphosphole derivatives, which are stablized by [W(CO)5] moieties, are formed (see scheme). The synthesis of the azaphosphole is accompanied by an additional C-H activation at room temperature and offers a novel and ...

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Item Type:Article
Date:14 September 2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/1521-3773(20010917)40:18<3413::AID-ANIE3413>3.0.CO;2-1DOI
Keywords:insertion; phosphorus heterocycles; tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:38
Last Modified:13 Mar 2014 13:36
Item ID:15336
Owner Only: item control page

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