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Synthesis of Novel Transition Metal-Group 15 Cage Compounds and their Use as Molecular Precursors for Binary and Ternary Transition Metal Pnictides

Vogel, Ulf and Scheer, Manfred (2001) Synthesis of Novel Transition Metal-Group 15 Cage Compounds and their Use as Molecular Precursors for Binary and Ternary Transition Metal Pnictides. Phosphorous and Sulfur and the Related Elements 169 (1), pp. 223-226.

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Abstract

The reaction of [lcubW(CO)5rcub2PCl] with K[Co(CO)4] yields the novel compounds [W(CO)4(η4-#12296Co(CO)3PlcubW(CO)5rcub#122972)[ (1) and [lcub(CO)4WCo3(CO)6rcub(μ3-PlcubW(CO)5rcub)] (2) along with the previously known derivatives [Co2(CO)6(μ,η2-P2lcubW(CO)5rcub2)] (3) and [Co3(CO)9(μ3-PlcubW(CO)5rcub)] (4). Complex [W2(CO)8(μ-CO)(μ,η2-P2lcubW(CO)5rcub2) (5) was synthesised by reacting ...

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Item Type:Article
Date:2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1080/10426500108546629DOI
Keywords:phosphorous; clusters; cobalt; tungsten; thermochemistry
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:44
Last Modified:14 Jun 2010 12:44
Item ID:15340
Owner Only: item control page
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