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Reactivity Study of the P2 Ligand Complex [lcubCpCr(CO)2rcub2(μ,η2-P2)]

Umbarkar, Shubhangi B. and Sekar, Perumal and Scheer, Manfred (2001) Reactivity Study of the P2 Ligand Complex [lcubCpCr(CO)2rcub2(μ,η2-P2)]. Phosphorous and Sulfur and the Related Elements 169 (1), pp. 205-208.

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Abstract

The complex [lcubCpCr(CO)2rcub2(μ-η2-P2)] has shown highly contrasting reactivity behavior towards ECl3 (E = P, As, Sb) and LiBEt3H. The reaction with ECl3 has yielded the first example of cyclo-P2E ligand complexes, [Cp(CO)2Cr(η3-P2E)]. On the other hand, the reaction with LiBEt3H led to P-P bond cleavage and formation of novel PH2 containing complexes [Cp2(CO)4Cr2(μ-PH2)(μ-H)], and ...

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Item Type:Article
Date:2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1080/10426500108546624DOI
Keywords:phosphorous; chromium; gold; cluster; cyclopentadiene
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:46
Last Modified:14 Jun 2010 12:46
Item ID:15342
Owner Only: item control page
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