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Novel Main Group-Transition Metal Cluster Compounds Incorporating Antimony, Iron and Cobalt

Gröer, Thomas and Palm, Tobias and Scheer, Manfred (2000) Novel Main Group-Transition Metal Cluster Compounds Incorporating Antimony, Iron and Cobalt. European Journal of Inorganic Chemistry 2000 (12), pp. 2591-2595.

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Abstract

The reaction of [{Cpx(CO)2Fe}SbCl2] [1a: Cpx = 5-C5H3tBu2-1,3 (Cp"); 1b: Cpx = 5-C5Me5 (Cp*)] with Na2[Fe(CO)4] or K[Co(CO)4] affords the novel antimony-transition metal cluster compounds [{3-SbFe(CO)2Cp"}3{Fe(CO)3}4] (2), [{Fe3(CO)9}{3-SbFe(CO)2Cp"}2] (3) and [{4-SbFe(CO)2Cp*}2{Co4(CO)10(-CO)}] (4). All products were characterised by X-ray structure analyses and other methods. Cluster 2 reveals ...

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Item Type:Article
Date:17 November 2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/1099-0682(200012)2000:12<2591::AID-EJIC2591>3.0.CO;2-E DOI
Keywords:Antimony; Iron; Cobalt; Cluster; Polyhedra
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:18
Last Modified:13 Mar 2014 13:38
Item ID:15452
Owner Only: item control page

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