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Synthesis and Properties of Novel Metal-Linked Pn Ligand Complexes

Sekar, Perumal and Umbarkar, Shubhangi B. and Scheer, Manfred and Voigt, Andreas and Kirmse, Reinhard (2000) Synthesis and Properties of Novel Metal-Linked Pn Ligand Complexes. European Journal of Inorganic Chemistry 2000 (12), pp. 2585-2589.

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The reaction of [CpCr(CO)3]2 with P4 in toluene at 90 °C for 5 h affords the triple-decker sandwich complex [CpCr(CO)(3-P3)(CpCr)2(,1:5:5-P5)] (1) as a new product, along with the previously described products with P2, P3, and P10 units. The structure of the paramagnetic complex 1 has been established by single-crystal X-ray diffraction methods. A novel complex ...


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Item Type:Article
Date:17 November 2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Phosphorus; Chromium; Molybdenum; Cyclopentadienes; Sandwich complexes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Deposited On:21 Jun 2010 12:19
Last Modified:13 Mar 2014 13:38
Item ID:15454
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