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Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters

Gröer, Thomas and Scheer, Manfred (2000) Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters. Organometallics 19 (18), pp. 3683-3691.

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Abstract

The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradiated, the heterocubane [Bi4{Co(CO)3}4] (3) is formed. [{Cp‘ ‘(CO)2Fe}BiCl2] (1b; Cp‘ ‘ = η5-C5H3-tBu2) reacts with [Fe(CO)4]2- to give the nido cluster [{Fe3(CO)9}{μ-BiFe(CO)2Cp‘ ‘}2] (4) and to give ...

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Item Type:Article
Date:9 August 2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/om000372gDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:20
Last Modified:13 Mar 2014 13:38
Item ID:15456
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