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On the pathway of the 1–5 migration of a Cp* ligand

Schiffer, Michael and Scheer, Manfred (2000) On the pathway of the 1–5 migration of a Cp* ligand. Journal of the Chemical Society, Dalton Transactions 2000 (15), pp. 2493-2494.

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Abstract

The thermolysis and photolysis, respectively, of the phosphinidene complex [Cp*P{W(CO)5}2] 1 in the presence of MeCCMe leads to the three-membered heterocycle [(2-CH2C5Me4)W(CO)4C{(CH3)CH(CH3)}PW(CO)5] 4 with an unusual 2-coordinated CH2C5Me4 ligand formed by a 1,4-sigmatropic hydrogen shift; the crystal structure and the spectroscopic data of 4 are ...

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Item Type:Article
Date:2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/b004941gDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:21 Jun 2010 12:35
Last Modified:13 Mar 2014 13:38
Item ID:15462
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