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Novel Complexes with a Short Tungsten-Phosphorus Triple Bond

Kramkowski, Peter and Baum, Gerhard and Radius, Udo and Kaupp, Martin and Scheer, Manfred (1999) Novel Complexes with a Short Tungsten-Phosphorus Triple Bond. Chemistry - A European Journal 5 (10), pp. 2890-2898.

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Abstract

The novel phosphido complexes [thf(ArO)3WPM(CO)5] (3 a,b; Ar=2,6-Me2C6H3; M=W, Cr; 3 a is depicted here) can be prepared in high yields by the reaction of [W2(OAr)6] with tBuCP in the presence of [M(CO)5thf]. Initial reactivity studies with [(ArO)4W=O] and [(Ph3P)2Pt(2-C2H4)] resulted in the formation of dinuclear four-membered ring complexes and indicated the high side-on reactivity of these ...

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Item Type:Article
Date:24 September 1999
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/(SICI)1521-3765(19991001)5:10<2890::AID-CHEM2890>3.0.CO;2-#DOI
Keywords:Metathesis; P ligands; Phosphido ligands; Tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:39
Last Modified:13 Mar 2014 13:39
Item ID:15475
Owner Only: item control page

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