Scheer, Manfred and Kramkowski, Peter and Schuster, Kay (1999) An Approach to Novel Complexes with a Tungsten−Phosphorus Triple Bond. Organometallics 18 (15), pp. 2874-2883.
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The metathesis reaction of [W2(OtBu)6] with tBuCP leads to the phosphido complex [(tBuO)3WP] (1), which can be stabilized when the reaction is carried out in the presence of Lewis acidic carbonyl complexes of the type [M(CO)5thf] (M = Cr, W). However, further reaction of the metathesis products [(tBuO)3WCtBu] and [(tBuO)3WP→M(CO)5] [M = W (4a), Cr (4b)] with tBuCP leads after subsequent 1,3-OtBu ...
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|Date:||19 July 1999|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||21 Jun 2010 12:39|
|Last Modified:||13 Mar 2014 13:39|