Startseite UB

An Approach to Novel Complexes with a Tungsten−Phosphorus Triple Bond

Scheer, Manfred and Kramkowski, Peter and Schuster, Kay (1999) An Approach to Novel Complexes with a Tungsten−Phosphorus Triple Bond. Organometallics 18 (15), pp. 2874-2883.

[img]PDF
Download (248kB) - Repository staff only

at publisher (via DOI)


Abstract

The metathesis reaction of [W2(OtBu)6] with tBuCP leads to the phosphido complex [(tBuO)3WP] (1), which can be stabilized when the reaction is carried out in the presence of Lewis acidic carbonyl complexes of the type [M(CO)5thf] (M = Cr, W). However, further reaction of the metathesis products [(tBuO)3WCtBu] and [(tBuO)3WP→M(CO)5] [M = W (4a), Cr (4b)] with tBuCP leads after subsequent 1,3-OtBu ...

plus


Export bibliographical data

Item Type:Article
Date:19 July 1999
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/om990019eDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:39
Last Modified:13 Mar 2014 13:39
Item ID:15476
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact