Gröer, Thomas and Baum, Gerhard and Scheer, Manfred (1998) Complexes with a Monohapto Bound Phosphorus Tetrahedron and Phosphaalkyne. Organometallics 17 (26), pp. 5916-5919.
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The reaction of white phosphorus with the coordinatively unsaturated [M(CO)3(PR3)2] complexes (M = Mo, W; R = Cy, Pri) yields the compounds [M(CO)3(PR3)2(η1-P4)] in which the P4-tetrahedron is end-on bonded to the metal. In the same manner reacts Ar‘CP (Ar‘ = C6H2But3-2,4,6) with this complex to give [W(CO)3(PCy3)2(η1-PCAr‘)]. The X-ray structures of the products are discussed, and for the P4-unit in [W(CO)3(PCy3)2(η1-P4)] the librational analysis was performed to correct their translational and rotational motions.
|Date:||20 November 1998|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||21 Jun 2010 12:40|
|Last Modified:||20 Jul 2011 22:30|