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A study of the photochemical reaction between W2(OCH2tBu)6 and P4. Characterization of the phosphido cluster W4(P)2(OCH2tBu)10

Chisholm, Malcolm H. and Folting, Kristen and Scheer, Manfred (1998) A study of the photochemical reaction between W2(OCH2tBu)6 and P4. Characterization of the phosphido cluster W4(P)2(OCH2tBu)10. Polyhedron 17 (17), pp. 2931-2935.

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Abstract

The photochemical reaction between W2(OCH2tBu)6 and P4 has been studied by NMR spectroscopy in toluene-d8 and those reactions have been complemented by studies on the bench top. A complex sequence of reactions is implicated by the formation of a variety of products, one of which has been observed previously in the thermal reaction between W2(OCH2tBu)6L2 where L = py and HNMe2 and P4, namely ...

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Item Type:Article
Date:14 August 1998
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/S0277-5387(98)00079-5DOI
Keywords:tungsten; alkoxide; phosphide; cluster
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:43
Last Modified:13 Mar 2014 13:39
Item ID:15481
Owner Only: item control page

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