Scheer, Manfred and Leiner, Eva and Kramkowski, Peter and Schiffer, Michael and Baum, Gerhard (1998) A Novel Synthetic Approach to Highly Reactive Intermediates Containing a Metal-Phosphorus Triple Bond. Chemistry - A European Journal 4 (10), pp. 1917-1923.
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A new synthetic route providing access to the highly reactive intermediate [Cp*(CO)2WPW(CO)5] with a tungsten-phosphorus triple bond is presented (see scheme). The intermediate is formed by thermolysis of [Cp*P2] by Cp* migration from the phosphorus to give 5 coordination at the transition metal. Addition of other reactive molecules to solutions conatining the intermediate provides a simple approach to novel W/P-containing ligands.
|Date:||14 December 1998|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||C-H activation; Cyclopentadienes; Intermediates; P ligands; Tungsten|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||21 Jun 2010 12:42|
|Last Modified:||20 Jul 2011 22:30|