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A Novel Synthetic Approach to Highly Reactive Intermediates Containing a Metal-Phosphorus Triple Bond

Scheer, Manfred and Leiner, Eva and Kramkowski, Peter and Schiffer, Michael and Baum, Gerhard (1998) A Novel Synthetic Approach to Highly Reactive Intermediates Containing a Metal-Phosphorus Triple Bond. Chemistry - A European Journal 4 (10), pp. 1917-1923.

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Abstract

A new synthetic route providing access to the highly reactive intermediate [Cp*(CO)2WPW(CO)5] with a tungsten-phosphorus triple bond is presented (see scheme). The intermediate is formed by thermolysis of [Cp*P{W(CO)5}2] by Cp* migration from the phosphorus to give 5 coordination at the transition metal. Addition of other reactive molecules to solutions conatining the intermediate provides a ...

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Item Type:Article
Date:14 December 1998
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/(SICI)1521-3765(19981002)4:10<1917::AID-CHEM1917>3.0.CO;2-9DOI
Keywords:C-H activation; Cyclopentadienes; Intermediates; P ligands; Tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:42
Last Modified:13 Mar 2014 13:39
Item ID:15482
Owner Only: item control page

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