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The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu)—the structure of [Cp′Mo(CO)2<(η3-P4){Cr(CO)5}4(H)>]

Scheer, Manfred and Becker, Uta and Magull, Jörg (1998) The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu)—the structure of [Cp′Mo(CO)2<(η3-P4){Cr(CO)5}4(H)>]. Polyhedron 17 (11-12), pp. 1983-1989.

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Abstract

The photochemical reaction of [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu) with white phosphorus in the presence of [Cr(CO)5thf] leads to the Pn ligand complexes [Cr(CO)4 <(η4-P4){(Cr(CO)5}4>;] (1), [Cp′Mo(CO)2<(η3-P4){Cr(CO)54(H)>] (2) and [{Cp′Mo(CO)2}2<(μ,η2-P2){Cr(CO)5}2>] (3). The products were characterized by NMR, IR and partially by X-ray structure analysis. The reaction proceeds via a P---P bond ...

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Item Type:Article
Date:30 May 1998
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/S0277-5387(97)00480-4DOI
Keywords:Pn-ligands; molybdenum complexes; bent cyclo-P4-ligand; Mo2P2-tetrahedral complex; phosphido complex intermediate
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:44
Last Modified:13 Mar 2014 13:39
Item ID:15484
Owner Only: item control page

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