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Crystal Structure of (-)-Corycavinium(+)-10-Camphorsulfonate, a Biosynthetic Intermediate to Hexahydrobenzo[c]phenanthridine Alkaloids

Kamigauchi, M. and Noda, Y. and Iwasa, K. and Nishijo, Z. and Ishida, T. and In, Y. and Wiegrebe, Wolfgang (1994) Crystal Structure of (-)-Corycavinium(+)-10-Camphorsulfonate, a Biosynthetic Intermediate to Hexahydrobenzo[c]phenanthridine Alkaloids. Helvetica Chimica Acta 77, pp. 243-251.

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Abstract

The crystal structure of (—)-corycavinium (+)-10-camphorsulfonate has been investigated by X-ray analysis. The structure of (-)-corycavinium ion ( = (-)-(7S,13S,14R)-5,6,13,13a-tetrahydro-l3a-hydroxy-7-methyl- 2,3;9,10-bis(methylenedioxy)-8H-dibenzo[a,g]quinolizinium), has been determined. The conformation with B/Ccis -conjunction, a twisted half-chair of ring B, and a half-chair of ring C, as ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Wiegrebe
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:12 Jul 2010 09:41
Last Modified:13 Mar 2014 13:50
Item ID:15785
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