Scheer, Manfred and Becker, Uta (1994) Cyclo-P4 Ligands with a Maximum of Electron-Donating Ability. Phosphorus, Sulfur and Silicon & the Related Elements 93-94 (1-4), pp. 257-260.
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Abstract
The reactions of P4 with metal carbonyls of chromium, tungsten and iron lead to square planar cyclo-P4 ligand complexes and to a rectangular distorted P4 ligand complex, respectively. Furthermore the study of the transformation pathway of tetrahedral P4 to the corresponding Px ligands reveals a stepwise (PP) bond cleavage with a bicyclotetraphosphine intermediate to give a cyclo-P4 containing product.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Owner: | Martin Kaiser | ||||
| Deposited On: | 12 Jul 2010 14:15 | ||||
| Last Modified: | 21 Jul 2011 00:32 | ||||
| Item ID: | 15791 |
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