Kammermeier, T. and Kaiser, A. and Lee, G.S. and Burgemeister, Thomas and Wiegrebe, Wolfgang (1994) Formation of 1H-Aziridines from Chalcones and Hydroxylamine. Archiv der Pharmazie 327, pp. 207-210.
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Abstract
Highly substituted chalcones 1 do not react with two molecules of hydroxylamine
affording dioximes 2 or hydroxyamino-oximes 3 as expected
according to von Auwers' procedure1): only one molecule of hydroxylamine
is consumed leading to trans-configurated 2-benzoyl-3-phenyl-1H-aziridines 4.
Aus den hochsubstituierten Chalkonen 1 entstehen nicht die nach von
Auwers1) zu erwartenden Dioxime 2 oder Hydroxyamino-oxime 3 unter
Verbrauch von zwei Mol Hydroxylamin. Stattdessen wird nur ein Mol
Hydroxylamin verbraucht, und es entstehen trans-konfigurierte 2-Benzoyl-
3-phenyl-1H-aziridine 4.
| Item Type: | Article |
|---|---|
| Institutions: | Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Wiegrebe |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Status: | Published |
| Refereed: | Yes, this version has been refereed |
| Created at the University of Regensburg: | Unknown |
| Owner: | Universitätsbibliothek Regensburg |
| Deposited On: | 12 Jul 2010 11:40 |
| Last Modified: | 21 Jul 2011 00:32 |
| Item ID: | 15793 |
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