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Px ligands with a maximum of electron-donating ability *1: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” =η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF]

Scheer, Manfred and Becker, Uta and Huffman, J. C. and Chisholm, Malcolm H. (1993) Px ligands with a maximum of electron-donating ability *1: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” =η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF]. Journal of Organometallic Chemistry 461 (1-2), C1-C3.

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Abstract

The reaction of P4 with [CoCp“(μ-CO)]2 in the presence of [Cr(CO)5THF] leads to [CoCp”(η4-P4){Cr(CO)5}3] (Cp“ = η5-C5H3 tBu2-1,3) (IUPAC formula [CoCp”[{Cr(CO)5}3(PH-1κP1,2κP2, 3κP3)] (κ-P1,P2,P3,P4)]) as a final product. An X-ray structural study reveals a complex with a planar cyclo-P4 ligand capped by a Cp”Co unit. Three of the phosphorus atoms are also coordinated to [Cr(CO)5] ...

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Item Type:Article
Date:September 1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/0022-328X(93)83299-BDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:12 Jul 2010 12:21
Last Modified:13 Mar 2014 13:50
Item ID:15794
Owner Only: item control page
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