Scheer, Manfred and Becker, Uta and Huffman, J. C. and Chisholm, Malcolm H. (1993) Px ligands with a maximum of electron-donating ability *1: VI. [CoCp“(η4-P4)3] (Cp” =η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF]. Journal of Organometallic Chemistry 461 (1-2), C1-C3.
Download (279kB) - Repository staff only
The reaction of P4 with [CoCp“(μ-CO)]2 in the presence of [Cr(CO)5THF] leads to [CoCp”(η4-P4)3] (Cp“ = η5-C5H3 tBu2-1,3) (IUPAC formula [CoCp”[3(PH-1κP1,2κP2, 3κP3)] (κ-P1,P2,P3,P4)]) as a final product. An X-ray structural study reveals a complex with a planar cyclo-P4 ligand capped by a Cp”Co unit. Three of the phosphorus atoms are also coordinated to [Cr(CO)5] groups.
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||12 Jul 2010 12:21|
|Last Modified:||20 Jul 2011 22:32|