The cyclo-P4 Ligand as 12-Electron Donor [Der cyclo-P4-Ligand als 12-Elektronen-Donor]

Scheer, Manfred and Herrmann, Eckhard and Sieler, Joachim and Oehme, Matthias (1991) The cyclo-P4 Ligand as 12-Electron Donor [Der cyclo-P4-Ligand als 12-Elektronen-Donor]. Angewandte Chemie International Edition 30 (8), pp. 969-971.

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Abstract

White phosphorus and a suitable metal complex fragment are always good for surprises. Reaction of [W(CO)5thf] with P4 in THF affords the complex shown on the right, in which the square-planar P4 ligand serves as a 12-electron donor. The analogous chromium complex is also accessible in this way.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.199109691DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner:Martin Kaiser
Deposited On:19 Jul 2010 14:04
Last Modified:21 Jul 2011 00:33
Item ID:15913
Owner Only: item control page