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Synthesis of triangular [RhM2cp3(CO)n] clusters (M = Ni, n = 2; M = Fe, n = 4; M = Mo, W, n = 6). [RhMo2cp3(CO)6] as catalyst precursor in the CO hydrogenation reaction

Walther, B. and Scheer, Manfred and Böttcher, Hans-Christian and Trunschke, A. and Ewald, H. and Gutschick, D. and Miessner, H. and Skupin, M. and Vorbeck, G. (1989) Synthesis of triangular [RhM2cp3(CO)n] clusters (M = Ni, n = 2; M = Fe, n = 4; M = Mo, W, n = 6). [RhMo2cp3(CO)6] as catalyst precursor in the CO hydrogenation reaction. Inorganica Chimica Acta 156 (2), pp. 285-289.

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Abstract

Different synthetic routes to triangular clusters [RhM2cp3(CO)n] (M=NJ, n=2; M=Fe, n=4; M= Mo, W, n=6) were studied. The clusters obtained were characterized by spectroscopic means (IR, 1H and 13C NMR, MS). The behaviour of a [RhMo2cp3- (CO)6] cluster-derived catalyst in CO hydrogenation reactions was studied in comparison to appropriate conventionally prepared bimetallic and monometallic catalysts.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/S0020-1693(00)83514-8DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner:Martin Kaiser
Deposited On:19 Jul 2010 14:10
Last Modified:21 Jul 2011 00:33
Item ID:15933
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