Walther, B. and Scheer, Manfred and Böttcher, Hans-Christian and Trunschke, A. and Ewald, H. and Gutschick, D. and Miessner, H. and Skupin, M. and Vorbeck, G. (1989) Synthesis of triangular [RhM2cp3(CO)n] clusters (M = Ni, n = 2; M = Fe, n = 4; M = Mo, W, n = 6). [RhMo2cp3(CO)6] as catalyst precursor in the CO hydrogenation reaction. Inorganica Chimica Acta 156 (2), pp. 285-289.
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Different synthetic routes to triangular clusters [RhM2cp3(CO)n] (M=NJ, n=2; M=Fe, n=4; M= Mo, W, n=6) were studied. The clusters obtained were characterized by spectroscopic means (IR, 1H and 13C NMR, MS). The behaviour of a [RhMo2cp3- (CO)6] cluster-derived catalyst in CO hydrogenation reactions was studied in comparison to appropriate conventionally prepared bimetallic and monometallic catalysts.
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|Date:||15 February 1989|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||19 Jul 2010 12:10|
|Last Modified:||13 Mar 2014 13:53|