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Chelating ionic versus bridged molecular structures of group 13 metal complexes with bidentate ligands

Trinh, Cong and Bodensteiner, Michael and Virovets, Alexander V. and Peresypkina, Eugenia V. and Scheer, Manfred and Matveev, Sergey M. and Timoshkin, Alexey Y. (2010) Chelating ionic versus bridged molecular structures of group 13 metal complexes with bidentate ligands. Polyhedron 29 (1), pp. 414-424.

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Abstract

Complexes of aluminum and gallium trihalides with ethylenediamine (en) and N,N,N′,N′-tetramethylethylenediamine (tmen) of 2:1 composition have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. In contrast to known molecular complexes of hydrido and methyl-substituted analogs, these solid complexes adopt ionic structures of the general type ...

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Item Type:Article
Date:13 January 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/j.poly.2009.06.020DOI
Keywords:Donor–acceptor complexes; Bidentate ligands; Aluminum; Gallium; X-ray structure analysis; Thermodynamics; Density functional computations
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:19 Jul 2010 12:24
Last Modified:19 Jul 2010 12:24
Item ID:15947
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