Trinh, Cong and Bodensteiner, Michael and Virovets, Alexander V. and Peresypkina, Eugenia V. and Scheer, Manfred and Matveev, Sergey M. and Timoshkin, Alexey Y. (2010) Chelating ionic versus bridged molecular structures of group 13 metal complexes with bidentate ligands. Polyhedron 29 (1), pp. 414-424.
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Complexes of aluminum and gallium trihalides with ethylenediamine (en) and N,N,N′,N′-tetramethylethylenediamine (tmen) of 2:1 composition have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. In contrast to known molecular complexes of hydrido and methyl-substituted analogs, these solid complexes adopt ionic structures of the general type ...
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|Date:||13 January 2010|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||Donor–acceptor complexes; Bidentate ligands; Aluminum; Gallium; X-ray structure analysis; Thermodynamics; Density functional computations|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||19 Jul 2010 12:24|
|Last Modified:||19 Jul 2010 12:24|