Deutsch
Zschunke, A. and Mügge, C. and Scheer, Manfred and Jurkschat, K. and Tzschach, A. (1983) The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane. Journal of Chemical Crystallography 13 (3), pp. 201-210.
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Abstract
From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (G =40 kJ/mol) than the barrier for simultaneous dissociation-inversion (G =70 kJ/mol). The dimers studied are sterically uniform.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Owner: | Petra Gürster | ||||
| Deposited On: | 26 Jul 2010 13:20 | ||||
| Last Modified: | 21 Jul 2011 00:34 | ||||
| Item ID: | 16004 |
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