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Synthesen und erhöhte Konfigurationslabilität von 2-Iminoindanderivaten mit Vorderseitenspannung

Knorr, R. and Ferchland, K. and Mehlstäubl, J. and Thi, Phung Hoang and Böhrer, P. and Lüdemann, H.-D. and Lang, Elmar (1992) Synthesen und erhöhte Konfigurationslabilität von 2-Iminoindanderivaten mit Vorderseitenspannung. Chemische Berichte 125 (9), pp. 2041-2049.

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Abstract

Syntheses and properties are described for sterically shielded imines R2C = NR (3c, e, g–k), which are rather inert toward nucleophiles. Nucleophilic attack at the nitrogen atom of 3k is indicated by the formation of the azine 4. (E,Z) Configurational diastereotopomerization (anti/syn) is strongly dependent on N substituents [CH3, phenyl, 1-naphthyl, acetyl, Si(CH3)3, cyano, SC6H5, SOC6H5, ...

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Item Type:Article
Date:1992
Institutions:Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie > Prof. Dr. Elmar Lang
Identification Number:
ValueType
10.1002/cber.19921250912DOI
Keywords:Basicity; Diastereotopomerization; Imines; Steric shielding; Steric strain
Subjects:500 Science > 570 Life sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:20 Oct 2010 06:21
Last Modified:13 Mar 2014 19:25
Item ID:17391
Owner Only: item control page
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