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Photophysical properties of Re(pbt)(CO)₄ studied by high resolution spectroscopy

Czerwieniec, R. and Finkenzeller, Walter J. and Hofbeck, T. and Starukhin, A. and Wedel, A. and Yersin, Hartmut (2009) Photophysical properties of Re(pbt)(CO)₄ studied by high resolution spectroscopy. Chemical Physics Letters 468, pp. 205-210.

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Photophysical properties of Re(pbt)(CO)₄ are investigated at cryogenic temperatures and high magnetic fields. The highly resolved spectra show that the zero field splitting of the lowest triplet T₁ into three substates is smaller than 2 cm⁻¹. With this result, the T₁ state can be classified as only slightly MLCT-perturbed ³LC (³ππ*) state. Consistently, spin-lattice relaxation times are slow at T ...


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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:17 Dec 2010 08:04
Last Modified:17 Dec 2010 08:04
Item ID:17400
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