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Triplets in metal-organic compounds. Chemical tunability of relaxation dynamics

Yersin, Hartmut ; Strasser, J.


Zusammenfassung

Triplets of metal–organic or related compounds of the platinum metal group split into substates. The amount of splitting at zero magnetic field (zfs) is mainly determined by the effective spin-orbit coupling, which is, for example, induced by metal-d and:or MLCT participations in these triplets. The total zfs can be tuned chemically over a very wide range from about 0.1 cm⁻¹ to more than 200 cm⁻¹ ...

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