Yersin, Hartmut and Humbs, W. and Strasser, J. (1997) Low-lying electronic states of [Rh(bpy)₃]³⁺, [Pt(bpy)₂]²⁺, and [Ru(bpy)₃]²⁺. A Comparative study based on highly frequency-resolved and time-resolved spectra. Coordination Chemistry Reviews 159, pp. 325-358.
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Optical emission and excitation spectra of [Rh(bpy-h₈)₃]³⁺, [Rh(bpy-h₈)₂(bpy-d₈)]³⁺, [Rh(bpy-d₈)₃]³⁺, [Pt(bpy-h₈)₂]²⁺, [Pt(bpy-h₈)(bpy-d₈)]²⁺, [Pt(bpy-d₈)₂]²⁺, [Ru(bpy-h₈)₃]²⁺, [Ru(bpy-h₈)₂(bpy-d₈)]²⁺, [Ru(bpy-d₈)₃]²⁺ are discussed. A series of trends - also including [Os(bpy)₃]²⁺ - is uncovered. These trends, which are connected with an increase in metal-d or MLCT character in the lowest ...
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|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Keywords:||MLCT character; Highly resolved spectra; Time resolved spectra|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||31 Mar 2011 11:35|
|Last Modified:||31 Mar 2011 11:35|