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Low-lying electronic states of [Rh(bpy)₃]³⁺, [Pt(bpy)₂]²⁺, and [Ru(bpy)₃]²⁺. A Comparative study based on highly frequency-resolved and time-resolved spectra

Yersin, Hartmut and Humbs, W. and Strasser, J. (1997) Low-lying electronic states of [Rh(bpy)₃]³⁺, [Pt(bpy)₂]²⁺, and [Ru(bpy)₃]²⁺. A Comparative study based on highly frequency-resolved and time-resolved spectra. Coordination Chemistry Reviews 159, pp. 325-358.

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Abstract

Optical emission and excitation spectra of [Rh(bpy-h₈)₃]³⁺, [Rh(bpy-h₈)₂(bpy-d₈)]³⁺, [Rh(bpy-d₈)₃]³⁺, [Pt(bpy-h₈)₂]²⁺, [Pt(bpy-h₈)(bpy-d₈)]²⁺, [Pt(bpy-d₈)₂]²⁺, [Ru(bpy-h₈)₃]²⁺, [Ru(bpy-h₈)₂(bpy-d₈)]²⁺, [Ru(bpy-d₈)₃]²⁺ are discussed. A series of trends - also including [Os(bpy)₃]²⁺ - is uncovered. These trends, which are connected with an increase in metal-d or MLCT character in the lowest ...

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Item Type:Article
Date:March 1997
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1016/S0010-8545(96)01318-5DOI
Keywords:MLCT character; Highly resolved spectra; Time resolved spectra
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Prof. Dr. Hartmut Yersin
Deposited On:31 Mar 2011 11:35
Last Modified:31 Mar 2011 11:35
Item ID:17481
Owner Only: item control page
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