Humbs, W. and Strasser, J. and Yersin, Hartmut (1997) Lowest excited triplet states in [Ru(bpy)₃]²⁺ and [Rh(bpy)₃]³⁺. A comparative study based on highly resolved spectra. Journal of Luminescence 72-74, pp. 677-678.
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The lowest excited states of [Ru(bpy)₃]²⁺ (bpy: 2,2’-bipyridine) exhibit a very strong involvement of metal 4d orbitals, while the metal character is extremely small in the states of [Rh(bpy)₃J³⁺. This contrasting behavior is clearly displayed in the emission and excitation spectra, when ligands are isotopically marked. It is demonstrated that these states, being of metal-to-ligand charge ...
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|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited on:||14 Feb 2011 12:39|
|Last modified:||14 Feb 2011 12:39|