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Arene-arene stacking in cis-bis[2-(2-thienyl)pyridine]platinum(II)

Breu, J. and Range, Klaus Jürgen and v. Zelewsky, A. and Yersin, Hartmut (1997) Arene-arene stacking in cis-bis[2-(2-thienyl)pyridine]platinum(II). Acta Crystallographica Section C C53, pp. 562-565.

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In the crystal structure of the title complex, [Pt(C₉H₆NS)₂], although the aromatic ligands are coordinated to a central heavy metal atom, T-shaped and shifted π-stacked arrangements of the aromatic moieties are preferred, leading to a sandwich herring-bone type of crystal-packing motif. The crystal structure is therefore consistent with the view that the arene-arene interactions are determined by electrostatics (multipole-multipole).

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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Deposited On:25 Feb 2011 13:14
Last Modified:25 Feb 2011 13:14
Item ID:17559
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