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Aqueous chemistry of mixed-amine cis- and transplatin analogues. Intramolecular preference for a kinetic six-membered ring over a thermodynamic five-membered ring ortho-platination product

Bednarski, Patrick J. and Ehrensperger, Edmund and Schönenberger, Helmut and Burgemeister, Thomas (1991) Aqueous chemistry of mixed-amine cis- and transplatin analogues. Intramolecular preference for a kinetic six-membered ring over a thermodynamic five-membered ring ortho-platination product. Inorganic chemistry 30 (15), pp. 3015-3025.

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Abstract

A series of mixed-amine cis- and trans-platin analogs, contg. benzylamine and 2-phenylethylamine functionalities, were synthesized and the aq. soln. chem. investigated. The cis- and trans-Pt(NH3)LCl2 (I; L = (1,2-bis(4-methoxyphenyl)ethylamine (MREA), 2-(4-methoxyphenyl)-1-phenylethylamine (MPPEA), bis(4-methoxyphenyl)methylamine (MPMA)) were synthesized in >98% isomeric purity. With the aim of ...

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Item Type:Article
Date:1991
Additional information (public):CAN 115:84115 78-7 Inorganic Chemicals and Reactions 135192-25-5; 135192-26-6; 135192-27-7; 135192-28-8; 135192-29-9; 135192-31-3; 135192-32-4; 135225-03-5; 135269-32-8; 135269-33-9; 135270-97-2 Role: RCT (Reactant), RACT (Reactant or reagent) (HPLC of); 135192-30-2P Role: FORM (Formation, nonpreparative), PREP (Preparation) (formation of, from 6-numbered chelate); 93922-81-7 Role: PRP (Properties) (kinetics of hydrolysis of); 135192-19-7P; 135192-20-0P; 135192-21-1P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of hydrolysis and orthoplatination of); 135192-22-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and thermal rearrangement of); 135192-23-3P; 135192-24-4P; 135269-29-3P; 135269-30-6P; 135269-31-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 13820-91-2; 15663-27-1 Role: RCT (Reactant), RACT (Reactant or reagent) (reactions of, with phenylalkylamines)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Schönenberger
Projects:SFB 234
Identification Number:
ValueType
1991:484115Other
Keywords:Kinetics of metalation (cycloplatination, of ammine phenylalkylamine complexes) Hydrolysis Kinetics of hydrolysis (of platinum ammine phenylalkylamine complexes) Metalation (cycloplatination, of ammine phenylalkylamine complexes) Chromatography (high-performance, of platinum amine phenylalkylamine complexes) orthoplatination ammine methoxyphenylalkylamine isomer complex platinum isomer complex methoxyphenylalkylamine kinetics hydrolysis platinum isomer complex
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Petra Gürster
Deposited On:12 Nov 2010 07:14
Last Modified:12 Nov 2010 07:14
Item ID:17686
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