Hensler, G. and Gallhuber, E. and Yersin, Hartmut (1986) Fine structure in the emission spectrum of [Ru(bpy)₃](PF₆)₂ single crystal. Inorganica Chimica Acta 113, pp. 91-94.
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For the first time, highly resolved polarized emission spectra of single-crystal [Ru(bpy)₃] (PF₆)₂ are presented. At low temperatures (T < 20 K) we observed fine structure on the blue side of the emission spectrum with a typical halfwidth of <=5 cm⁻¹. The spectral properties of the sharp emission lines and their temperature dependences allow us to assign two zero-phonon lines corresponding to 1E’ —› A’₁ at 17809 cm⁻¹ and to 2E’ —› A’₁ at 17816 cm⁻¹ in the D'₃ symmetry group.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||07 Mar 2011 09:34|
|Last Modified:||07 Mar 2011 09:34|