Gallhuber, E. and Hensler, G. and Yersin, Hartmut (1985) Low-temperature emission spectra of crystalline [Ru(bpy)₃](ClO₄)₂. Chemical Physics Letters 120, pp. 445-449.
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The three lowest excited states of crystalline [Ru(bpy)₃](CIO₄)₂ and their energies of 17605, 17614, and 17663 cm⁻¹ are identlfied by three zero-phonon lines in the emission spectra. A broad-band system and the zero-phonon lines show the same temperature dependence and belong to the same states. Each zero-phonon line is accompanied by a low-frequency progression of 36 cm⁻¹. Satellites due lo dlfferent intramolecular vlbrations are observed at T= 1.6 K and correspond to those Raman modes which are strongly resonance-enhanced.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||07 Mar 2011 09:29|
|Last Modified:||07 Mar 2011 09:29|