Yersin, Hartmut and Hensler, G. and Gallhuber, E. and Rettig, Wolfgang and Schwan, L. O. (1985) Emission properties of [Ru(bpy)₃]X₂•nH₂O powders. Inorganica Chimica Acta 105, pp. 201-203.
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Emission spectra and lifetimes for [Ru(bpy)₃]X₂•nH₂O (with X = PF₆, ClO₄, Cl, Br, I, SCN, NO₃, BF₄, B(phenyl)₄) are presented for the first time. The results, recorded between 300 K and 2 K, show drastic effects being connected to the counter-ion X. This paper demonstrates the importance of the second coordination sphere for the properties of the emitting [Ru(bpy)₃]²⁺ center.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||10 Mar 2011 07:24|
|Last Modified:||10 Mar 2011 07:24|