Yersin, Hartmut and Gallhuber, E. and Vogler, Arnd and Kunkely, Horst (1983) Polarized emission of [Ru(bpy)₃](PF₆)₂ single crystals. Journal of the American Chemical Society 105, pp. 4155-4156.
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Polarized emission spectra of single-crystal [Ru(bpy)₃](PF₆)₂ are reported for the first time. The spectra are recorded in the temperature range from T = 243 to 343 K. A new E parallel c-polarized emission band is found, situated 650 cm⁻¹ ± 20 % above the main emission peak maximum. The corresponding emitting state is assigned to A₂' (in D₃'). The E perpendicular c-polarized emission results from one or more E' states and is by a factor of about 20 more intense than the E parallel c-polarized emission.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||10 Mar 2011 07:22|
|Last Modified:||10 Mar 2011 07:22|