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Chirale Butadiene 1. H-NMR-Spektroskopischer Nachweis der behinderten Rotation bei hexasubstituierten Butadienen

Köbrich, Gert and Mannschreck, Albrecht and Misra, Ram A. and Rissmann, G. and Rösner, M. and Zündorf, W. (1972) Chirale Butadiene 1. H-NMR-Spektroskopischer Nachweis der behinderten Rotation bei hexasubstituierten Butadienen. Chemische Berichte 105 (12), pp. 3794-3806.

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Abstract

The skew conformation of butadiene has the point group C2 and is therefore chiral. The chirality of butadienes has been demonstrated spectroscopically for the first time with four compounds, 7, 8, 9 and 11, whose preparation is described. Their bulky substituents slow down the rotation around the central carbon single bond, by which the interconversion of the enantiomers is effected through an ...

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Item Type:Article
Date:1972
Additional information (public):späterer Zeitschr.titel: European journal of inorganic chemistry
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Retired Professors > Prof.Dr. Mannschreck
Identification Number:
ValueType
10.1002/cber.19721051207DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Gertraud Kellers
Deposited On:12 Nov 2010 08:46
Last Modified:12 Nov 2010 08:46
Item ID:17956
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