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Modelling of the thermodynamic properties of ionic solutions using a stepwise solvation-equilibrium model

Simonin, Jean-Pierre and Bernard, Olivier and Krebs, Stéphane and Kunz, Werner (2006) Modelling of the thermodynamic properties of ionic solutions using a stepwise solvation-equilibrium model. Fluid Phase Equilibria 242 (2), pp. 176-188.

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Other URL: http://dx.doi.org/10.1016/j.fluid.2006.01.019


Abstract

The stepwise solvation-equilibrium model of Stokes and Robinson is used for a description of departures from ideality in ionic solutions. It is shown how to construct a thermodynamically consistent model including solvation effects. Simple expressions are derived for the mean ion solvation number. The model is applied to strong electrolyte solutions (pure water+salt and mixed aqueous ...

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Item Type:Article
Date:25 April 2006
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Identification Number:
ValueType
10.1016/j.fluid.2006.01.019DOI
Keywords:Thermodynamics; Ionic solution; Electrolyte; Hydration; Solvation equilibria
Subjects:500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Ute Lange
Deposited On:30 Jun 2006
Last Modified:13 Mar 2014 09:37
Item ID:18
Owner Only: item control page
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