Schönenberger, Helmut and Eder, Maxcimilian (1970) Separation of organic bases by Craig distribution. VIII. Separation of N-alkylbenzylamine mixtures by multiplicative distribution. Fresenius' Zeitschrift für analytische Chemie 249 (2), pp. 117-120.
Full text not available from this repository.
The sepn. of the 8 homologous PhCH2NHR (where R = H and Me(CH2)n, n = 0-6) was achieved by only one distribution cycle of 400 stages with CHCl3-MeOH-2% HCl in the ratio 40:25:15 at 20-3 Deg. Sepn. also succeeded with less expensive app. in 2 (or more) steps with fewer stages by using different solvent systems at definite pH. Distribution coeffs. in the different systems and the distribution diagrams are given.
Export bibliographical data
|Additional Information (public):||CAN 72:83478 68 Phase Equilibriums, Chemical Equilibriums, and Solutions 100-46-9; 103-67-3; 2032-33-9; 2403-22-7; 5730-02-9; 14321-27-8; 25468-43-3; 25468-44-4 Role: PROC (Process) (sepn. of, from alkylbenzylamines by multiplicative distribution)|
|Institutions:||Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Schönenberger|
|Keywords:||Partition (of alkylbenzylamine mixts., between hydrochloric acid solns. and org. phase) Craig distribution alkylbenzylamines distribution Craig alkylbenzylamines alkylbenzylamines Craig distribution amines alkylbenzyl distribution benzylalkylamines distribution sepn alkylbenzylamines|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||19 Nov 2010 09:26|
|Last Modified:||19 Nov 2010 09:26|