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Cystostatic agents. III. Mechanism of reduction of Schiff bases by activated aluminum

Schönenberger, Helmut and Thies, Heinrich and Rappl, A. (1965) Cystostatic agents. III. Mechanism of reduction of Schiff bases by activated aluminum. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 298 (6), pp. 367-371.

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Abstract

cf. Schoenenberger, et al., CA 62, 6992f, 7664a, 13163g. The mechanism of redn. was investigated of benzylidenealkyl- and benzylidenearylamine-type Schiff bases with activated Al, to form mono- and dimeric secondary amines. Redn. of PhCH:NBu (I) in abs. EtOH with Al-Hg gave yields of benzylbutylamine (II) and N,N'-dibutyl-alpha ,alpha '-diphenylethylenediamine (III) (in meso- and racemic forms) ...

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Item Type:Article
Date:1965
Additional information (public):CAN 63:31027 32 Physical Organic Chemistry 2403-22-7P (Benzylamine, N-butyl-) Role: PREP (Preparation) (formation from N-benzylidenebutylamine and isopropylmagnesium halides, in N-benzylidenebutylamine redn. with Al-Hg); 544-40-1 (Butyl sulfide) (hydrogenolysis of, solvent effect in); 1165-52-2P (Ethylenediamine, N,N'-dibutyl-1,2-diphenyl-, meso-); 4169-62-4P (Ethylenediamine, N,N'-dibutyl-1,2-diphenyl-, (-)-) Role: PREP (Preparation) (prepn. of); 1077-18-5 (Butylamine, N-benzylidene-) (redn. of, by Al-Hg); 7439-97-6 (Mercury) (N-benzylidenebutylamine redn. by Al and); 7429-90-5 (Aluminum) (N-benzylidenebutylamine redn. by Hg and)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Schönenberger
Identification Number:
ValueType
1965:431027Other
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Petra Gürster
Deposited On:19 Nov 2010 08:27
Last Modified:19 Nov 2010 08:27
Item ID:18187
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