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Reactions of Schiff bases. V. The conversion of benzyl idenearylamines with Mg-MgI2 mixtures

Thies, Heinrich and Schönenberger, Helmut and Bauer, K. H. (1958) Reactions of Schiff bases. V. The conversion of benzyl idenearylamines with Mg-MgI2 mixtures. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 291, pp. 620-627.

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Abstract

cf. CA 53, 3112a. Reaction of benzylidenearylamines with Mg-MgI2 mixt. proceeded faster and with better yields than that of benzylidenealkylamines. Lower yields were obtained with halogen-, MeO- or dimethylamino-substituted benzylideneanilines. A mixt. of 2.4 g. Mg and of 12.7 g. iodine in 20 ml. anhyd. Et2O and 30 ml. anhyd. C6H6 was stirred until the iodine color disappeared, 0.1 mole Schiff ...

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Item Type:Article
Date:1958
Additional information (public):CAN 54:97388 10E Organic Chemistry: Benzene Derivatives 10377-58-9; 103043-89-6 (Derived from data in the 6th Collective Formula Index (1957-1961); 538-51-2 (Aniline, N-benzylidene-) (and derivs., reaction with Mg-MgI2 mixts.); 2879-66-5 (Ethylenediamine, N,N',1,2-tetraphenyl-); 56644-01-0 (Ethylenediamine, 1,2-diphenyl-N,N'-di-p-tolyl-); 83871-63-0 (Ethylenediamine, N,N'-diphenyl-1,2-di-p-tolyl-); 83871-64-1 (Ethylenediamine, N,N',1,2-tetra-p-tolyl-); 115228-56-3 (Ethylenediamine, N,N'-bis[o-chlorophenyl]-1,2-diphenyl-); 115228-94-9 (Ethylenediamine, N,N'-bis[m-chlorophenyl]-1,2-diphenyl-); 116027-50-0 (Ethylenediamine, 1,2-diphenyl-N,N'-di-o-tolyl-) (and eutectics with acetanilide and phenacetin); 2948-39-2 (Ethylenediamine, N,N'-bis(p-chlorophenyl)-1,2-diphenyl-); 96003-68-8 (Ethylenediamine, 1,2-bis(p-chlorophenyl)-N,N'-diphenyl-); 103051-28-1 (Ethylenediamine, N,N',1,2-tetrakis(p-chlorophenyl)-) (and eutectics with dicyanamide and phenetsal); 62-44-2 (Phenacetin) (eutectics of, with N,N',1,2-tetraarylethylenediamines); 103-84-4 (Acetanilide); 118-57-0 (Phenetsal); 504-66-5 (Dicyanamide) (eutectics with N,N',1,2-tetraarylethylenediamines)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Schönenberger
Identification Number:
ValueType
1960:97388Other
Keywords:Schiff bases (reactions of) Schiff bases (reactions of, with Mg-MgI2 mixts.) Magnesium Magnesium iodide (reaction with Schiff bases)
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Petra Gürster
Deposited On:19 Nov 2010 06:42
Last Modified:19 Nov 2010 06:42
Item ID:18199
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