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Coordination Chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* =η5-C5Me5) with Copper(I) Halides - Formation of Oligomeric and Polymeric Compounds

Schindler, Andrea and Balázs, Gábor and Zabel, Manfred and Gröger, Christian and Kalbitzer, Hans Robert and Scheer, Manfred (2010) Coordination Chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* =η5-C5Me5) with Copper(I) Halides - Formation of Oligomeric and Polymeric Compounds. Comptes Rendus Chimie 13 (8-9), pp. 1241-1248.

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Abstract

The reaction of the 1,2,4-triphosphaferrocene [Cp*Fe(η5-P3C2tBu2)] (1) with CuX (X = Cl, Br, I) in a 1:1 stoichiometric ratio leads to the formation of the oligomeric compounds [{Cu(μ-X)}6(μ6-X)Cu(MeCN)3{μ,η2-(Cp*Fe(η5-P3C2tBu2))}2{μ3,η3-(Cp*Fe(η5-P3C2tBu2))}] (X = Cl (2), Br (3)) and [{Cu(μ-I)}3{Cu(μ3-I)}3Cu(μ6-I){μ,η2-(Cp*Fe(η5-P3C2tBu2))}3{η1-(Cp*Fe(η5-P3C2tBu2))}] (4) revealing Cu(I) halide ...

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Item Type:Article
Date:September 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/j.crci.2010.05.003DOI
Keywords:P ligands; Copper(I) halides; Triphosphaferrocenes; Iron; Solid-state structures; Supramolecular chemistry
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Andreas Stauber
Deposited On:24 Feb 2011 14:05
Last Modified:24 Feb 2011 14:05
Item ID:19880
Owner Only: item control page
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