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A New Building Block for Organometallic-Inorganic Hybrid Polymers: The Mixed Group 15/16 Element Ligand Complex [Cp*2Mo2(µ,η2:2-PSe)2(µ-Se)] (Cp* =η5-C5Me5)

Bodensteiner, Michael and Dušek, Michal and Kubicki, Marek M. and Pronold, Michael and Scheer, Manfred and Wachter, Joachim and Zabel, Manfred (2010) A New Building Block for Organometallic-Inorganic Hybrid Polymers: The Mixed Group 15/16 Element Ligand Complex [Cp*2Mo2(µ,η2:2-PSe)2(µ-Se)] (Cp* =η5-C5Me5). European Journal of Inorganic Chemistry (33), pp. 5298-5303.

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/ejic.201000796/full


Abstract

The synthesis and spectroscopic characterization of [Cp*2Mo2P2Se3] (1; Cp* = C5Me5) and its use as a molecular building block in the formation of copper(I) halide polymers is described. The reaction of 1 in CH2Cl2 with 2 equiv. of CuBr and CuI in CH3CN under diffusion conditions gave [(Cp*2Mo2P2Se3)2(CuBr)2] (2) and [(Cp*2Mo2P2Se3)(CuX)3(CH3CN)]n (X = I; 3/4), respectively. The structure of 2 is ...

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Item Type:Article
Date:15 October 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.201000796DOI
Keywords:Phosphorus; Selenium; Copper; Coordination modes; Polymers
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Andreas Stauber
Deposited On:24 Feb 2011 14:12
Last Modified:31 Jan 2014 06:32
Item ID:19882
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