Welsch, Stefan and Bodensteiner, Michael and Dušek, Michal and Sierka, Marek and Scheer, Manfred (2010) A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry. Chemistry: A European Journal 16 (44), pp. 13041-13045.
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A new soluble In+source containing the very weakly coordinating anion [Al4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 units.
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|Date:||22 November 2010|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||coordination polymers; Group 13 elements; indium; phosphorus; weakly coordinating anions|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||24 Feb 2011 14:17|
|Last Modified:||31 Jan 2014 06:37|