A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry

Welsch, Stefan and Bodensteiner, Michael and Dušek, Michal and Sierka, Marek and Scheer, Manfred (2010) A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry. Chemistry: A European Journal 16 (44), pp. 13041-13045.

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201002484/full

Abstract

A new soluble In+source containing the very weakly coordinating anion [Al{OC(CF3)3}4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 units.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.201002484DOI
Keywords: * coordination polymers; * Group 13 elements; * indium; * phosphorus; * weakly coordinating anions
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner:Andreas Stauber
Deposited On:24 Feb 2011 15:17
Last Modified:24 Feb 2011 15:17
Item ID:19884
Owner Only: item control page