Welsch, Stefan and Bodensteiner, Michael and Dušek, Michal and Sierka, Marek and Scheer, Manfred (2010) A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry. Chemistry: A European Journal 16 (44), pp. 13041-13045.
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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201002484/full
Abstract
A new soluble In+source containing the very weakly coordinating anion [Al4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 units.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | * coordination polymers; * Group 13 elements; * indium; * phosphorus; * weakly coordinating anions | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Andreas Stauber | ||||
| Deposited On: | 24 Feb 2011 15:17 | ||||
| Last Modified: | 24 Feb 2011 15:17 | ||||
| Item ID: | 19884 |
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