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A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry

Welsch, Stefan and Bodensteiner, Michael and Dušek, Michal and Sierka, Marek and Scheer, Manfred (2010) A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry. Chemistry: A European Journal 16 (44), pp. 13041-13045.

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A new soluble In+source containing the very weakly coordinating anion [Al{OC(CF3)3}4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 ...


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Item Type:Article
Date:22 November 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
Keywords:coordination polymers; Group 13 elements; indium; phosphorus; weakly coordinating anions
Subjects:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Andreas Stauber
Deposited On:24 Feb 2011 14:17
Last Modified:31 Jan 2014 06:37
Item ID:19884
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