Welsch, Stefan and Gröger, Christian and Sierka, Marek and Scheer, Manfred (2011) Organometallic Nano-sized Capsule Consisting of cyclo-P5 Units and Cu(I) Ions. Angewandte Chemie: International Edition 50 (6), pp. 1435-1438.
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A giant organometallic molecule and a 2D coordination polymer are formed by template-assisted self-assembly between CuCl and the cyclo-P5 complex [Cp*Fe(η5-P5)]. The giant capsular molecule exhibits a skeleton of 110 inorganic core atoms and consists of two half-shells with threefold symmetry. Dipersion forces between two encapsulated [Cp*Fe(η5-P5)] guest complexes and half-shells are responsible for the cohesion of the capsule (see structure and model; Cp*=η5-C5Me5).
|Date:||5 January 2011|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||capsules; host–guest systems; phosphorus; self-assembly; supramolecular chemistry|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||24 Feb 2011 14:19|
|Last Modified:||31 Jan 2014 06:36|