Deutsch
Welsch, Stefan and Gröger, Christian and Sierka, Marek and Scheer, Manfred (2011) Organometallic Nano-sized Capsule Consisting of cyclo-P5 Units and Cu(I) Ions. Angewandte Chemie: International Edition 50 (6), pp. 1435-1438.
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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.201005910/full
Abstract
A giant organometallic molecule and a 2D coordination polymer are formed by template-assisted self-assembly between CuCl and the cyclo-P5 complex [Cp*Fe(η5-P5)]. The giant capsular molecule exhibits a skeleton of 110 inorganic core atoms and consists of two half-shells with threefold symmetry. Dipersion forces between two encapsulated [Cp*Fe(η5-P5)] guest complexes and half-shells are responsible for the cohesion of the capsule (see structure and model; Cp*=η5-C5Me5).
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | * capsules; * host–guest systems; * phosphorus; * self-assembly; * supramolecular chemistry | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Andreas Stauber | ||||
| Deposited On: | 24 Feb 2011 15:19 | ||||
| Last Modified: | 24 Feb 2011 15:19 | ||||
| Item ID: | 19886 |
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