Yersin, Hartmut and Gliemann, G. and Rössler, Ulrich (1977) On the nature of energy bands in tetracyanoplatinates. Solid State Communiticatons 21 (9), pp. 915-918.
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Abstract
Optical data and band calculations are presented for a series of tetracyanoplatinates with varying Pt-Pt-distance R. The band gap energies decrease according to R⁻³ with decreasing R. The energy bands which determine the optical and electrical properties of E parallel c originate from (Pt5dz², 6s) and (Pt6pz, CNπ*) hybrid molecular states.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Prof. Dr. Hartmut Yersin | ||||
| Deposited On: | 24 Feb 2011 13:52 | ||||
| Last Modified: | 24 Feb 2011 13:52 | ||||
| Item ID: | 19891 |
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